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LC269 Allyl acetoacetate

for synthesis


Order number Packaging Quantity Price €
AC27269 Glass bottle 100 ml 24.30
AC27269 Glass bottle 500 ml 61.65


Product information
Synonyms Acetoacetic acid allyl ester
Hill Formula C7H10O3
Chemical formula CH3COCH2COOCH2CH=CH2
HS Code 2918 30 00
EC number 214-269-9
Molar mass 142.15 g/mol
CAS number 1118-84-9


Chemical and physical data

Ignition temperature 300 °C DIN 51794
Solubility 48 g/l (20 °C)
Molar mass 142.15 g/mol
Density 1.038 g/cm3 (20 °C)
pH value 3.7 (48 g/l, H2O, 20 °C)
Boiling point 87 – 91 °C (13 hPa)
Vapor pressure 0.2 hPa (20 °C)
Explosion limit 1.15 %(V)
Flash point 67 °C DIN 51758
Refractive index 1.438 (25 °C, 589 nm)


Safety information

R Phrase R 22-24-38
Harmful if swallowed.Toxic in contact with skin.Irritating to skin.
S Phrase S 36/37-45
Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Categories of danger toxic, irritant
Hazard Symbol Toxic
Storage class 6.1A Combustible substances, toxic
WGK WGK 1 slightly water endangering
Disposal 9
Carcinogenic compounds and flammable compounds labelled “Highly toxic” or “Toxic”: container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).


Transport information
Declaration (transport by sea) IMDG-Code UN 2810 TOXIC LIQUID, ORGANIC, N.O.S.(ALLYL-ACETOACETATE), 6.1, III
Declaration (transport by air) IATA-DGR UN 2810 TOXIC LIQUID, ORGANIC, N.O.S.(ALLYL-ACETOACETATE), 6.1, III


Toxicological data
LD 50 oral LD50 rat 259 mg/kg
LD 50 dermal LD50 rat 266 mg/kg


Assay (GC, area%) ≥ 98 %
Density (d 20 °C/ 4 °C) 1.036 – 1.039
Identity (IR) passes test


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