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LC585 Bis(triphenylphosphine)copper(I) borohydridefor synthesis |
| Order number | Packaging | Quantity | Price € |
| AC27585 | Glass bottle | 5 g | 20.25 |
| Product information | |
| Hill Formula | C36H34BCuP2 |
| Chemical formula | [(C6H5)3P]2CuBH4 |
| HS Code | 2931 00 99 |
| EC number | 240-951-0 |
| Molar mass | 602.97 g/mol |
| CAS number | 16903-61-0 |
| Chemical and physical data | |
| Solubility | (20 °C) (decomposition) |
| Melting point | 160 – 165 °C decomposes |
| Molar mass | 602.97 g/mol |
| Safety information | |
| R Phrase | R 36/37/38 Irritating to eyes, respiratory system and skin. |
| S Phrase | S 6-26 Keep under protective gas.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| Categories of danger | irritant |
| Hazard Symbol |  Irritant |
| Storage class | 10 – 13 Other liquids and solids |
| WGK | WGK 3 highly water endangering |
| Disposal | 26 Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A. |
| Specifications | |
| Assay (ex Cu) | ≥ 99 % |
| Melting range – lower value |
≥ 158 °C |
| – upper value | ≤ 163 °C |
| Identity (IR) | passes test |
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