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LC586 Bis(triphenylphosphine)nickel(II) chloride

for synthesis


Order number Packaging Quantity Price €
AC27585 Glass bottle 10 g 30.825


Product information
Hill Formula C36H34BCuP2
Chemical formula [(C6H5)3P]2CuBH4
HS Code 2931 00 99
EC number 240-951-0
Molar mass 602.97 g/mol
CAS number 16903-61-0


Chemical and physical data
Solubility (20 °C) (decomposition)
Melting point 160 – 165 °C decomposes
Molar mass 602.97 g/mol


Safety information
R Phrase R 36/37/38
Irritating to eyes, respiratory system and skin.
S Phrase S 6-26
Keep under protective gas.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Categories of danger irritant
Hazard Symbol Irritant
Storage class 10 – 13 Other liquids and solids
WGK WGK 3 highly water endangering
Disposal 26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.


Assay (ex Cu) ≥ 99 %
Melting range
– lower value
≥ 158 °C
– upper value ≤ 163 °C
Identity (IR) passes test


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