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(granular) (protective medium: argon) for synthesis
|Order number||Packaging||Quantity||Price €|
|AC30579||Glass bottle||50 g||66.15|
|HS Code||2805 19 90|
|Molar mass||6.94 g/mol|
|EC index number||003-001-00-4|
|Chemical and physical data|
|Solubility||(20 °C) (decomposition)|
|Melting point||179 °C|
|Molar mass||6.94 g/mol|
|Density||0.534 g/cm3 (20 °C)|
|Boiling point||1347 °C|
|Vapor pressure||1 hPa (723 °C)|
|Safety information according to GHS|
|Hazard Statement(s)||H260: In contact with water releases flammable gases which may ignite spontaneously.
H314: Causes severe skin burns and eye damage.
EUH014: Reacts violently with water.
|Precautionary Statement(s)||P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P330 + P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P402 + P404: Store in a dry place. Store in a closed container.
|Storage class||4.3 Materials that form flammble gases in contact with water|
|WGK||WGK 2 water endangering|
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
|R Phrase||R 14/15-34
Reacts violently with water, liberating extremely flammable gases.Causes burns.
|S Phrase||S 8-43-45
Keep container dry.In case of fire, use fire-fighting equipment on basis class D.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
|Categories of danger||highly flammable, corrosive|
|Declaration (transport by sea) IMDG-Code||UN 1415 LITHIUM, 4.3, I|
|Declaration (transport by air) IATA-DGR||UN 1415 LITHIUM, 4.3, I|
|Assay of Li||≥ 99 %|