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LC3589 Lithium amide
|Order number||Packaging||Quantity||Price €|
|AC30589||Glass bottle||100 g||36.45|
|HS Code||2853 00 90|
|Molar mass||22.96 g/mol|
|Chemical and physical data|
|Solubility||(20 °C) (decomposition)|
|Melting point||373 °C|
|Molar mass||22.96 g/mol|
|Density||1.178 g/cm3 (20 °C)|
|Bulk density||600 kg/m3|
|Boiling point||430 °C|
|Safety information according to GHS|
|Hazard Statement(s)||H261: In contact with water releases flammable gases.
H314: Causes severe skin burns and eye damage.
EUH014: Reacts violently with water.
|Precautionary Statement(s)||P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P330 + P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P402 + P404: Store in a dry place. Store in a closed container.
|Storage class||4.3 Materials that form flammble gases in contact with water|
|WGK||WGK 2 water endangering|
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
|R Phrase||R 14-34
Reacts violently with water.Causes burns.
|S Phrase||S 26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
|Categories of danger||corrosive|
|Declaration (transport by sea) IMDG-Code||UN 1390 ALKALI METAL AMIDE, 4.3, II|
|Declaration (transport by air) IATA-DGR||UN 1390 ALKALI METAL AMIDES, 4.3, II|
|Assay (HClO4)||≥ 95 %|
|Identity (IR)||passes test|