send us an inquiry

LC3589 Lithium amide

for synthesis

 

Order number Packaging Quantity Price €
AC30589 Glass bottle 100 g 36.45

 

Product information
Hill Formula H2LiN
Chemical formula LiNH2
HS Code 2853 00 90
EC number 231-968-4
Molar mass 22.96 g/mol
CAS number 7782-89-0

 

Chemical and physical data
Solubility (20 °C) (decomposition)
Melting point 373 °C
Molar mass 22.96 g/mol
Density 1.178 g/cm3 (20 °C)
Bulk density 600 kg/m3
Boiling point 430 °C

 

Safety information according to GHS
Hazard Statement(s) H261: In contact with water releases flammable gases.
H314: Causes severe skin burns and eye damage.
EUH014: Reacts violently with water.
Precautionary Statement(s) P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P330 + P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P402 + P404: Store in a dry place. Store in a closed container.
Signal Word Danger
Hazard Pictogram(s)
Storage class 4.3 Materials that form flammble gases in contact with water
WGK WGK 2 water endangering
Disposal 26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.

 

Safety information
R Phrase R 14-34
Reacts violently with water.Causes burns.
S Phrase S 26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Categories of danger corrosive
Hazard Symbol Corrosive

 

Transport information
Declaration (transport by sea) IMDG-Code UN 1390 ALKALI METAL AMIDE, 4.3, II
Declaration (transport by air) IATA-DGR UN 1390 ALKALI METAL AMIDES, 4.3, II

 

Specifications
Assay (HClO4) ≥ 95 %
Identity (IR) passes test