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LC3589 Lithium amidefor synthesis |
| Order number | Packaging | Quantity | Price € |
| AC30589 | Glass bottle | 100 g | 36.45 |
| Product information | |
| Hill Formula | H2LiN |
| Chemical formula | LiNH2 |
| HS Code | 2853 00 90 |
| EC number | 231-968-4 |
| Molar mass | 22.96 g/mol |
| CAS number | 7782-89-0 |
| Chemical and physical data | |
| Solubility | (20 °C) (decomposition) |
| Melting point | 373 °C |
| Molar mass | 22.96 g/mol |
| Density | 1.178 g/cm3 (20 °C) |
| Bulk density | 600 kg/m3 |
| Boiling point | 430 °C |
| Safety information according to GHS | |
| Hazard Statement(s) | H261: In contact with water releases flammable gases. H314: Causes severe skin burns and eye damage. EUH014: Reacts violently with water. |
| Precautionary Statement(s) | P280: Wear protective gloves/protective clothing/eye protection/face protection. P301 + P330 + P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P402 + P404: Store in a dry place. Store in a closed container. |
| Signal Word | Danger |
| Hazard Pictogram(s) |   |
| Storage class | 4.3 Materials that form flammble gases in contact with water |
| WGK | WGK 2 water endangering |
| Disposal | 26 Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A. |
| Safety information | |
| R Phrase | R 14-34 Reacts violently with water.Causes burns. |
| S Phrase | S 26-36/37/39-45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). |
| Categories of danger | corrosive |
| Hazard Symbol |  Corrosive |
| Transport information | |
| Declaration (transport by sea) IMDG-Code | UN 1390 ALKALI METAL AMIDE, 4.3, II |
| Declaration (transport by air) IATA-DGR | UN 1390 ALKALI METAL AMIDES, 4.3, II |
| Specifications | |
| Assay (HClO4) | ≥ 95 % |
| Identity (IR) | passes test |