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LC3611 Lithium tetrahydroborate

for synthesis


Order number Packaging Quantity Price €
AC30611 10 g 82.80


Product information
Synonyms Lithium boron hydride, Lithium boranate
Hill Formula BH4Li
Chemical formula LiBF4
HS Code 2850 00 20
EC number 241-021-7
Molar mass 21.78 g/mol
CAS number 16949-15-8


Chemical and physical data
Solubility 209 g/l (10 °C)
Melting point 280 °C
Molar mass 21.78 g/mol
Density 0.6660 g/cm3 (20 °C)
Bulk density 300 kg/m3
pH value >7 (H2O, 20 °C) (saturated aqueous solution)
Explosion limit 4.00 – 75.60 %(V)
Flash point -17 °C


Safety information
R Phrase R 15-34
Contact with water liberates extremely flammable gases.Causes burns.
S Phrase S 26-36/37/39-43-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of fire, use sand. Never use water.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Categories of danger highly flammable, corrosive
Hazard Symbol


RTECS ED2725000
Storage class 4.3 Materials that form flammble gases in contact with water
WGK WGK 2 water endangering
Disposal 26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.


Transport information
Declaration (transport by sea) IMDG-Code UN 1413 LITHIUM BOROHYDRIDE, 4.3, I
Declaration (transport by air) IATA-DGR UN 1413 LITHIUM BOROHYDRIDE, 4.3, I


Assay (hypochlorite) ∼ 95%