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turnings acc. to Grignard for synthesis
|Order number||Packaging||Quantity||Price €|
|AC30620||Metal can||250 g||16.20|
|AC30620||Metal can||1 kg||38.70|
|HS Code||8104 30 00|
|Molar mass||24.31 g/mol|
|EC index number||012-001-00-3|
|Chemical and physical data|
|Ignition temperature||>450 °C|
|Solubility||(20 °C) (slow decomposition)|
|Melting point||651 °C|
|Molar mass||24.31 g/mol|
|Density||1.74 g/cm3 (20 °C)|
|Boiling point||1107 °C|
|Flash point||500 °C|
|Safety information according to GHS|
|Hazard Statement(s)||H260: In contact with water releases flammable gases which may ignite spontaneously.
H250: Catches fire spontaneously if exposed to air.
|Precautionary Statement(s)||P210: Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P402 + P404: Store in a dry place. Store in a closed container.
|Storage class||4.2S Spontaneously Combustible Solids|
|WGK||NWG not water endangering|
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
|R Phrase||R 15-17
Contact with water liberates extremely flammable gases.Spontaneously flammable in air.
|S Phrase||S 7/8-43
Keep container tightly closed and dry.In case of fire, use fire-fighting equipment on basis class D.
|Categories of danger||highly flammable|
|Declaration (transport by sea) IMDG-Code||UN 1418 MAGNESIUM POWDER, 4.3 (4.2), II, Segregation Group: 15 (Powdered metals)|
|Declaration (transport by air) IATA-DGR||UN 1418 MAGNESIUM POWDER, 4.3 (4.2), II|
|Assay (on Mg)||≥ 99 %|