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LC5421 Sodium hydride suspension
(60% suspension in paraffin oil) for synthesis

 

Order number Packaging Quantity Price €
AC32421 Glass bottle 100 g 28.8

 

Product information
Hill Formula HNa
Chemical formula NaH
HS Code 3824 90 97
EC number 231-587-3
Molar mass 24.0 g/mol
EC index number 001-003-00-X
CAS number 7646-69-7

 

Chemical and physical data
Solubility (20 °C) (rigorous decomposition)
Molar mass 24.0 g/mol
Density 0.92 g/cm3 (20 °C)
Bulk density 500 – 700 kg/m3
Boiling point >225 °C (1013 hPa) (decomposition)

 

 

Safety information
R Phrase R 15-34
Contact with water liberates extremely flammable gases.Causes burns.
S Phrase S 7/8-26-36/37/39-43-45
Keep container tightly closed and dry.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of fire, use sand. Never use water.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Categories of danger highly flammable, corrosive
Hazard Symbol

Flammable

Corrosive

RTECS Materials that form flammble gases in contact with water
Storage class WGK 1 slightly water endangering
Disposal 26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.

 

Transport information
Declaration (transport by sea) IMDG-Code UN 1427 SODIUM HYDRIDE, 4.3, I
Declaration (transport by air) IATA-DGR UN 1427 SODIUM HYDRIDE, 4.3, I

 

Specifications
Assay (by gasvolumetry) ∼60%